Dry air or dry nitrogen will follow the combined gas laws more accurately than air containing moisture, but the difference really is academic.

Oxidation of the rubber inside a tyre has never been of concern to me, nor anyone else I know. I have only ever seen tyres fail from normal wear, cuts from impact or sharp objects or by oxidation or ozone attack of the outer carcase. The cracks in the sidewall, always start outside, never on the inside.

Snake oil for sure.
Regards

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Race teams will often use nitrogen to fill tires, but largely out of conveience rather than due to any performance benefit. No ancilliary equipment needed to fill a tire if you have a bottle of nitrogen. If you use a compressor you either need a generator or need to find a place to plug in, or need a gas powered compressor.

There is absolutely no harm in using nitrogen to fill tires, so as long as the shop didn't hit you up with any extra charges just shrug it off.

The question about nitrogen in tires has come up in other lists on the web as well. Let me clarrify a few points.

1. Air is 78% nitrogen, N2, and 21% oxygen, O2. So even if you put air in the tire, it's already 78% nitrogen. Many of the so called nitrogen generators don't produce much more than 90% nitrogen.

2. At relatively low pressures (ie tire pressures) N2, O2 and water vapor will all behave as ideal gases, and follow PV=nRT. Pressure will increase or decrease to the same extent as the temperature increases or decreases regardless of which gas is in the tire. (Even at 300 psi, which is about 20 atm, there is little deviation from ideality.) Therefore the comments about N2 not changing in pressure as the temperature changes are without merit.

3. The rate of effusion (or diffusion) of a gas through a porous membrane depends on the molar mass and to some degree on the molecular diameter. N2 and O2 are almost the same size and N2 is lighter than O2 (28 g/mol vs 32 g/mol) so if either gas were to effuse out of the tire, nitrogen would do it more quickly. Luckily, tires are designed not to be porous membranes.

4. N2 and O2 both have essentially the same specific heat capacity, about 1.0 J/gK, and thermal conductivity, about 0.00026 W/cmK. Water vapor has a specific heat capacity of about 2 J/gK. But remember, water vapor will constitute less than 1% of the air in the tire. So the idea that N2 has different heat handling properties is also without merit.

5. The ozone, O3, in the atmosphere, which is a ground level pollutant, will do a great deal more damage to your tires than the O2 inside the tire. For instance, don't leave a condom out in the air in Los Angeles for a few days. It will develop lots of tiny holes and weaken.

spdracer22 says that dry air is preferably to air with a lot of water vapor. As a tire heats up, the very small amount of H2O present will be in the vapor state which may contribute to the overall pressure very slightly.

Several have suggested that N2 in a high pressure tank is more portable and requires no electricity. That would make sense, particularly for aircraft tires.

I find no reason to believe that N2 is going to produce a "better ride" or "better handling".

The bottom line is that for general passenger car tires or truck tires there is nothing to be gained (other than portability) by using nitrogen rather than air.

ORIGINAL: swartlkk

"I've considered Liquid N2 to keep them cool when I'm out carving the corners!" -some tool on another forum

I could not believe that I actually read that on another forum!!!

When I was at RIT for my masters, They had a big flask (20 gallon) of liquid nitrogen for their scanning electron microscope. We would play with that stuff every chance we got (about twice a week to refill the SEM). We froze grapes, oranges, golf *****, etc. The grapes and oranges smash into a bizillion peices when frozen Surprisingly enough, the golfball only broke into 2 peices when thrown against a concrete wall fully frozen! We then found out that if you put about 1" of liquid n2 into a smaller soda bottle, that there is a rather large bang when it is put into water or left outside on a very warm day. As the liquid n2 warms up, it converts to gas at a rediculously high pressure inside the soda bottle. It sounds like a howitzer when it goes off! It's incredible how much pressure a soda bottle can take. The plastic expands a tremendous amount before it finally blows and blows big! The one time we did it, it blew a 3" deep 1ft diameter crater in the lawn outside our building with a 1L bottle.